| 1 | The Music of the Night (The Phantom of the Opera) | Michael Crawford | 5:13 |
| 2 | Don't Cry for Me Argentina (Evita) | Julie Covington | 5:26 |
| 3 | Defying Gravity (Wicked) | Kerry Ellis | 4:17 |
| 4 | New York, New York (On the Town) | John Reardon, Nancy Walker, Betty Comden, Adolph Green & Cris Alexander | 3:59 |
| 5 | Maria (West Side Story) | Jose Carreras | 2:58 |
| 6 | Big Spender (Sweet Charity) | Helen Gallagher & Thelma Oliver | 3:36 |
| 7 | Dreamboats and Petticoats | Scott Bruton & Daisy Wood-Davis | 2:47 |
| 8 | Singin' in the Rain | Jamie Cullum | 4:08 |
| 9 | Oh, What a Beautiful Morning (Oklahoma) | Alfred Drake & Joan Roberts | 2:33 |
| 10 | Oklahoma | Alfred Drake | 2:31 |
| 11 | Stranger in Paradise (Kismet) | Doretta Morrow & Richard Kiley | 4:09 |
| 12 | Some Enchanted Evening (South Pacific) | Bryn Terfel | 3:42 |
| 13 | As If We Never Said Goodbye (Sunset Boulevard) | Alfie Boe | 4:52 |
| 14 | Summertime (Porgy & Bess) | Louis Armstrong & Ella Fitzgerald | 4:54 |
| 15 | Climb Ev'ry Mountain (The Sound of Music) | Lesley Garrett | 1:30 |
| 16 | Any Dream Will Do (Joseph & the Amazing Technicolor Dreamcoat) | Lee Mead | 3:49 |
| 17 | Consider Yourself (Oliver!) | Martin Horsey | 4:07 |
| 18 | You'll Never Walk Alone (Carousel) | Lesley Garrett | 4:18 |
| 19 | I Dreamed a Dream (Les Misérables) | Patti LuPone | 4:28 |