| 1 | Civilization V Brave New World Opening Movie Music | Michael Curran | 2:51 |
| 2 | Civilization V Brave New World Theme | Michael Curran | 3:37 |
| 3 | Casimir Peace – Poland – Bog sie rodzi | Geoff Knorr | 3:28 |
| 4 | Casimir War – Poland – Bog sie rodzi | Geoff Knorr | 3:08 |
| 5 | Enrico Dandolo Peace – Venice – Rotta Ò Sonata | Michael Curran | 4:20 |
| 6 | Enrico Dandolo War – Venice – Rotta Ò Sonata | Michael Curran | 3:13 |
| 7 | Maria I Peace – Portugal – Saudades de Coimbra | Michael Curran | 3:32 |
| 8 | Maria I War – Portugal – Saudades de Coimbra | Michael Curran | 3:16 |
| 9 | Pedro II Peace – Brazil – Chega de Saudade | Geoff Knorr | 3:56 |
| 10 | Pedro II War – Brazil – Chega de Saudade | Geoff Knorr | 3:20 |
| 11 | Ashurbanipal Peace – Assyria – Ancient Assyrian Chant | Geoff Knorr | 3:11 |
| 12 | Ashurbanipal War – Assyria – Ancient Assyrian Chant | Geoff Knorr | 3:11 |
| 13 | Ahmed Al Mansur Peace – Morocco – Mawal Gnawi | Michael Curran | 3:23 |
| 14 | Ahmed Al Mansur War – Morocco – Mawal Gnawi | Michael Curran | 3:10 |
| 15 | Shaka Peace – Zulu – Duo Juluka Inhliziyo Yami | Michael Curran | 3:25 |
| 16 | Shaka War – Zulu – Duo Juluka Inhliziyo Yami | Michael Curran | 3:11 |
| 17 | Gajah Mada Peace – Indonesia – Udan Mas | Geoff Knorr | 3:37 |
| 18 | Gajah Mada War – Indonesia – Udan Mas | Geoff Knorr | 3:03 |
| 19 | Pocatello Peace – Shoshone – Shoshone Sun Dance Songs | Geoff Knorr | 3:27 |
| 20 | Pocatello War – Shoshone – Shoshone Sun Dance Songs | Geoff Knorr | 3:23 |
| 21 | Ujuba na takaburi – Scramble for Africa Scenario Music | Geoff Knorr | 3:15 |
| 22 | Civil War Scenario Music | Michael Curran | 3:14 |
| 23 | Conquest of the New World Scenario Music – Orchestral Version | Michael Curran | 3:31 |