| 1 | Papa Was a Rollin’ Stone | The Temptations | 6:59 |
| 2 | Please Mr. Postman (single version) | The Marvelettes | 2:29 |
| 3 | Shotgun | Jr. Walker & the All Stars | 2:59 |
| 4 | I Can’t Help Myself (Sugar Pie, Honey Bunch) | Four Tops | 2:43 |
| 5 | Where Did Our Love Go | The Supremes | 2:33 |
| 6 | My Girl | The Temptations | 2:40 |
| 7 | Fingertips (Pt. 2 / live at the Regal Theater, 1963) | Stevie Wonder | 3:11 |
| 8 | Do You Love Me | The Contours | 2:53 |
| 9 | I Want You Back | The Jackson 5 | 2:58 |
| 10 | My Guy | Mary Wells | 2:47 |
| 11 | Shop Around | The Miracles | 2:45 |
| 12 | I Heard It Through the Grapevine | Gladys Knight & the Pips | 2:46 |
| 13 | Just My Imagination (Running Away with Me) | The Temptations | 3:52 |
| 14 | Ain’t No Mountain High Enough | Marvin Gaye & Tammi Terrell | 2:27 |
| 15 | Mickey’s Monkey | The Miracles | 2:47 |
| 16 | Stubborn Kind of Fellow | Marvin Gaye | 2:47 |
| 17 | Money (That’s What I Want) | Barrett Strong | 2:37 |
| 18 | Dancing in the Street | Martha Reeves and the Vandellas | 2:38 |
| 19 | Ain’t Too Proud to Beg | The Temptations | 2:34 |
| 20 | Uptight (Everything’s Alright) | Stevie Wonder | 2:53 |
| 21 | Who’s Lovin’ You | The Jackson 5 | 4:00 |
| 22 | The Tears of a Clown | Smokey Robinson & The Miracles | 2:56 |
| 23 | Baby Love | The Supremes | 2:37 |
| 24 | Come See About Me | The Supremes | 2:41 |
| 25 | Get Ready | The Temptations | 2:35 |
| 26 | What’s Going On | Marvin Gaye | 3:51 |
| 27 | The Tracks of My Tears | Smokey Robinson & The Miracles | 2:54 |
| 28 | This Old Heart of Mine (Is Weak for You) | The Isley Brothers | 2:46 |
| 29 | For Once in My Life | Stevie Wonder | 2:51 |
| 30 | (Love Is Like a) Heat Wave | Martha Reeves and the Vandellas | 2:45 |
| 31 | What Becomes of the Brokenhearted | Jimmy Ruffin | 3:02 |
| 32 | I’ll Be There | The Jackson 5 | 3:57 |
| 33 | Bernadette | Four Tops | 3:03 |
| 34 | Ball of Confusion (That’s What the World Is Today) | The Temptations | 4:06 |
| 35 | Inner City Blues (Make Me Wanna Holler) | Marvin Gaye | 5:28 |
| 36 | You Keep Me Hangin’ On | The Supremes | 2:45 |
| 37 | (I’m a) Road Runner | Jr. Walker & the All Stars | 2:48 |
| 38 | I Heard It Through the Grapevine | Marvin Gaye | 3:14 |
| 39 | Baby, I’m for Real | The Originals | 3:20 |
| 40 | Girl (Why You Wanna Make Me Blue) | The Temptations | 2:17 |
| 41 | Reach Out I’ll Be There | Four Tops | 2:59 |
| 42 | Ain’t No Mountain High Enough | Diana Ross | 6:16 |
| 43 | The Way You Do the Things You Do | The Temptations | 2:39 |
| 44 | My Heart Can’t Take It No More | The Supremes | 2:55 |
| 45 | Got a Job | The Miracles | 2:43 |
| 46 | All in Love Is Fair | Stevie Wonder | 3:42 |
| 47 | You Can’t Hurry Love | The Supremes | 2:48 |
| 48 | You Really Got a Hold on Me | The Miracles | 2:56 |
| 49 | You’re Nobody Till Somebody Loves You (live at the Copa) | The Supremes | 5:44 |
| 50 | Superstition | Stevie Wonder | 4:12 |
| 51 | Cloud Nine | The Temptations | 3:29 |
| 52 | I’ll Try Something New | The Miracles | 2:39 |
| 53 | ABC | The Jackson 5 | 2:58 |
| 54 | Heaven Must Have Sent You | The Elgins | 2:31 |
| 55 | Your Precious Love | Marvin Gaye & Tammi Terrell | 2:59 |
| 56 | I Wish It Would Rain | The Temptations | 2:51 |
| 57 | I Second That Emotion | Smokey Robinson & The Miracles | 2:41 |
| 58 | Signed, Sealed, Delivered (I’m Yours) (single version) | Stevie Wonder | 2:45 |
| 59 | It’s a Shame | The Spinners | 3:14 |
| 60 | Never Can Say Goodbye | The Jackson 5 | 3:00 |