| 1 | Pow R. Toc H. / (intro) (live, 1967‐05‐14, BBC TV “Look at the Week”) | Pink Floyd | 0:49 |
| 2 | Introduction (live, 1967‐05‐14, BBC TV “Look at the Week”) | Pink Floyd | 1:03 |
| 3 | Astronomy Domine (live, 1967‐05‐14, BBC TV “Look at the Week”) | Pink Floyd | 4:08 |
| 4 | Interstellar Overdrive (live, 1967‐01‐27, UFO Club) | Pink Floyd | 4:23 |
| 5 | End Piece Interview (live, 1967‐05‐14, BBC TV “Look at the Week”) | Pink Floyd | 0:43 |
| 6 | Flaming (live, 1967‐09‐25, BBC Radio, John Peel’s Night Ride) | Pink Floyd | 2:49 |
| 7 | Scarecrow (live, 1967‐09‐25, BBC Radio, John Peel’s Night Ride) | Pink Floyd | 2:07 |
| 8 | The Gnome (live, 1967‐09‐25, BBC Radio, John Peel’s Night Ride) | Pink Floyd | 2:15 |
| 9 | Mathilda Mother (live, 1967‐09‐25, BBC Radio, John Peel’s Night Ride) | Pink Floyd | 3:29 |
| 10 | Vegetable Man (live, 1967‐12‐20, BBC Radio, John Peel’s Night Ride) | Pink Floyd | 3:26 |
| 11 | Pow R. Toc H. (live, 1967‐12‐20, BBC Radio, John Peel’s Night Ride) | Pink Floyd | 3:04 |
| 12 | Scream Thy Last Scream Old Woman With a Basket (live, 1967‐12‐20, BBC Radio, John Peel’s Night Ride) | Pink Floyd | 3:53 |
| 13 | Jugband Blues (live, 1967‐12‐20, BBC Radio, John Peel’s Night Ride) | Pink Floyd | 4:02 |
| 14 | Top Gear Opening Credits / John Peel (live, 1968‐06‐25, BBC Radio, “Top Gear”) | Pink Floyd | 0:19 |
| 15 | The Murderotic Woman (Or Careful with That Axe, Eugene) (live, 1968‐06‐25, BBC Radio, “Top Gear”) | Pink Floyd | 3:38 |
| 16 | The Massed Gadgets of Hercules (aka A Saucerful of Secrets) (live, 1968‐06‐25, BBC Radio, “Top Gear”) | Pink Floyd | 7:18 |
| 17 | Let There Be More Light (live, 1968‐06‐25, BBC Radio, “Top Gear”) | Pink Floyd | 4:33 |
| 18 | Julia Dream (live, 1968‐06‐25, BBC Radio, “Top Gear”) | Pink Floyd | 3:36 |
| 19 | Top Gear End Credits (live, 1968‐06‐25, BBC Radio, “Top Gear”) | Pink Floyd | 1:10 |
| 20 | Daybreak (aka Grantchester Meadows) (live, 1969‐05‐12, BBC Radio, “Top Gear”) | Pink Floyd | 3:48 |
| 21 | Nightmare (aka Cymbeline) (live, 1969‐05‐12, BBC Radio, “Top Gear”) | Pink Floyd | 3:38 |
| 22 | The Beginning / Beset by Creatures of the Deep (aka Green Is the Colour & Careful with That Axe, Eugene) (live, 1969‐05‐12, BBC Radio, “Top Gear”) | Pink Floyd | 6:59 |
| 23 | The Narrow Way (Part 3) (live, 1969‐05‐12, BBC Radio, “Top Gear”) | Pink Floyd | 4:48 |
| 24 | Vegetable Man (studio version – Unreleased single) | Pink Floyd | 2:38 |