| 1 | Little Children | Billy J. Kramer and The Dakotas | 2:39 |
| 2 | Long Live Love | Sandie Shaw | 2:30 |
| 3 | The Carnival Is Over | The Seekers | 2:57 |
| 4 | A Whiter Shade of Pale | Procol Harum | 3:49 |
| 5 | Fire | The Crazy World of Arthur Brown | 2:39 |
| 6 | Sorry Suzanne | The Hollies | 2:48 |
| 7 | All Right Now | Free | 3:48 |
| 8 | Get It On | T Rex | 4:13 |
| 9 | Virginia Plain | Roxy Music | 2:50 |
| 10 | Cum on Feel the Noize | Slade | 3:15 |
| 11 | When Will I See You Again | Three Degrees | 2:48 |
| 12 | Make Me Smile (Come Up & See Me) | Steve Harley & Cockney Rebel | 3:30 |
| 13 | You to Me Are Everything | The Real Thing | 3:08 |
| 14 | Good Old Fashioned Lover Boy | Queen | 2:44 |
| 15 | Down in the Tube Station at Midnight | The Jam | 3:26 |
| 16 | Hit Me With Your Rhythm Stick | Ian Dury & the Blockheads | 3:15 |
| 17 | Ant Music | Adam & the Ants | 2:50 |
| 18 | Don’t You Want Me | The Human League | 3:18 |
| 19 | Do You Really Want to Hurt Me? | Culture Club | 3:23 |
| 20 | Red Red Wine | UB40 | 2:37 |
| 21 | Wake Me Up Before You Go Go | Wham! | 3:04 |
| 22 | There Must Be an Angel (Playing with My Heart) | Eurythmics | 3:53 |
| 23 | West End Girls | Pet Shop Boys | 3:31 |
| 24 | You Win Again | The Bee Gees | 3:17 |
| 25 | The Only Way Is Up | Yazz & The Plastic Population | 3:30 |
| 26 | All Round the World | Lisa Stansfield | 2:54 |
| 27 | Nothing Compares 2 U | Sinéad O’Connor | 2:49 |
| 28 | Crazy | Seal | 2:52 |
| 29 | Connected | Stereo MCs | 2:52 |
| 30 | Regret | New Order | 4:24 |
| 31 | Parklife | Blur | 3:09 |
| 32 | Back for Good | Take That | 3:56 |
| 33 | Don’t Look Back in Anger | Oasis | 5:10 |
| 34 | Wannabe | Spice Girls | 3:02 |
| 35 | If You Tolerate This Your Children Will Be Next | Manic Street Preachers | 5:08 |
| 36 | Livin’ La Vida Loco | Ricky Martin | 4:06 |
| 37 | Groovejet (If This Ain’t Love) | Spiller | 4:08 |
| 38 | I Don’t Want a Lover | Texas | 3:56 |
| 39 | Rockin’ All Over the World | Status Quo | 3:34 |
| 40 | I Believe in a Thing Called Love | The Darkness | 3:57 |
| 41 | Mad World | Michael Andrews, featuring Gary Jules | 3:20 |
| 42 | Dancing Queens | CCS | 3:28 |
| 43 | Overture & Beginnings: Top of the Pops Theme c. 1966 | [unknown] | 0:34 |
| 44 | Overture & Beginnings: Top of the Pops Theme 1970 | [unknown] | 0:45 |
| 45 | Overture & Beginnings: Top of the Pops Theme 1973 | CCS | 0:49 |
| 46 | Overture & Beginnings: Top of the Pops Theme 1981 | Phil Lynott | 0:20 |
| 47 | Overture & Beginnings: Top of the Pops Theme 1986 | Paul Hardcastle | 0:29 |
| 48 | Overture & Beginnings: Top of the Pops Theme 1987 | Paul Hardcastle | 0:25 |
| 49 | Overture & Beginnings: Top of the Pops Theme 1991 | Tony Gibber | 0:25 |
| 50 | Overture & Beginnings: Top of the Pops Theme 1995 | Vince Clarke | 0:18 |
| 51 | Overture & Beginnings: Top of the Pops Theme 1998 | Ben Chapman | 0:20 |
| 52 | Overture & Beginnings: Top of the Pops Theme 2004 | Tony Gibber | 0:25 |
| 53 | TOTP Uncut: A Whiter Shade of Pale | Procol Harum | 4:37 |
| 54 | TOTP Uncut: Wake Me Up Before You Go Go | Wham! | 3:29 |
| 55 | TOTP Uncut: Don’t You Want Me | The Human League | 4:18 |
| 56 | TOTP Uncut: Livin’ La Vida Loco | Ricky Martin | 5:10 |
| 57 | TOTP Uncut: Make Me Smile (Come Up & See Me) | Steve Harley & Cockney Rebel | 4:04 |
| 58 | TOTP Uncut: Mad World | Michael Andrews, featuring Gary Jules | 3:19 |
| 59 | Every Picture Tells a Story | CCS | 1:21 |
| 60 | TOTP Uncovered | Andi Peters | 4:04 |