| 1 | Main Title And Closing Theme | Royal Philharmonic Orchestra, Fred Steiner | 1:23 |
| 2 | The Corbomite Maneuver: Radiation / Cube Radiation / Baby Balok / Fesarius Approaches - From “The Corbomite Maneuver” | Royal Philharmonic Orchestra, Fred Steiner | 5:06 |
| 3 | Charlie X: Kirk’s Command / Charlie’s Mystery / Charlie’s Gift - From “Charlie X” | Royal Philharmonic Orchestra, Fred Steiner | 3:36 |
| 4 | Charlie X: Kirk Is Worried / Card Tricks / Charlie’s Yen - From “Charlie X” | Royal Philharmonic Orchestra, Fred Steiner | 3:22 |
| 5 | Charlie X: Zap Sam / Zap Janice / Zap The Cap / Zap The Spaceship - From “Charlie X” | Royal Philharmonic Orchestra, Fred Steiner | 4:18 |
| 6 | Charlie X: Charlie’s Friend / Goodbye Charlie / Finale - From “Charlie X” | Royal Philharmonic Orchestra, Fred Steiner | 2:44 |
| 7 | The Doomsday Machine: Goodbye M. Decker / Kirk Does It Again - From “The Doomsday Machine” | Royal Philharmonic Orchestra, Fred Steiner | 5:45 |
| 8 | Mudd’s Women: Three Venuses / Meet Mr. Mudd / Hello Girls / Venus Aboard / Mudd Laffs - From “Mudd’s Women” | Royal Philharmonic Orchestra, Fred Steiner | 3:10 |
| 9 | Mudd’s Women: Hello Ruth / The Last Crystal / The Venus Drug - From “Mudd’s Women” | Royal Philharmonic Orchestra, Fred Steiner | 4:30 |
| 10 | Mudd’s Women: Planet Rigel / Eve Is Out / Space Radio - From “Mudd’s Women” | Royal Philharmonic Orchestra, Fred Steiner | 4:08 |
| 11 | Mudd’s Women: Eve Cooks / Pretty Eve / Mudd’s Farewell - From “Mudd’s Women” | Royal Philharmonic Orchestra, Fred Steiner | 3:16 |
| 12 | By Any Other Name: Neutralizer / Kelvan Theme / More Neutralizers / Broken Blocks - From “By Any Other Name” | Royal Philharmonic Orchestra, Fred Steiner | 3:41 |
| 13 | By Any Other Name: Rojan’s Revenge / Rojan’s Blocks / Pretty Words / Rojan’s Victory / Finale - From “By Any Other Name” | Royal Philharmonic Orchestra, Fred Steiner | 5:32 |
| 14 | The Trouble With Tribbles: A Matter Of Pride / No Tribble At All / Big Fight - From “The Trouble With Tribbles” | Royal Philharmonic Orchestra, Fred Steiner | 4:19 |
| 15 | Mirror, Mirror: Mirror, Mirror / Black Ship Theme / The Agonizer / Meet Marlena - From “Mirror, Mirror” | Royal Philharmonic Orchestra, Fred Steiner | 4:39 |
| 16 | Mirror, Mirror: Black Ship Tension / Goodbye Marlena / Short Curtain - From “Mirror, Mirror” | Royal Philharmonic Orchestra, Fred Steiner | 3:52 |
| 17 | The Empath: Enter Gem / Kirk Healed - From “The Empath” | Royal Philharmonic Orchestra, Fred Steiner | 2:07 |
| 18 | The Empath: Vian Lab / The Subjects / Cave Exit / Star Trek Chase - From “The Empath” | Royal Philharmonic Orchestra, Fred Steiner | 3:37 |
| 19 | The Empath: Help Him / Spock Stuck / McCoy Tortured - From “The Empath” | Royal Philharmonic Orchestra, Fred Steiner | 5:18 |
| 20 | The Empath: Time Grows Short - From “The Empath” | Royal Philharmonic Orchestra, Fred Steiner | 5:06 |
| 21 | The Empath: Vian’s Farewell / Empath Finale - From “The Empath” | Royal Philharmonic Orchestra, Fred Steiner | 2:20 |