| 1 | The Phantom of the Opera (The Phantom of the Opera) | Michael Crawford feat. Barbara Bonney | 4:28 |
| 2 | Don’t Cry for Me Argentina (Evita) | Julie Covington | 5:26 |
| 3 | I Will Always Love You (The Bodyguard) | Michael Ball | 3:42 |
| 4 | Anything Goes (Anything Goes) | Elaine Paige | 4:09 |
| 5 | I Know Him So Well (Chess) (live) | Barbara Dickson | 4:16 |
| 6 | Chitty Chitty Bang Bang (Chitty Chitty Bang Bang) | Poppy Tierney, Simon Bowman, Max Milner & Hayley Wareham | 2:21 |
| 7 | Talk to the Animals (Doctor Dolittle) | Phillip Schofield | 3:25 |
| 8 | Some Enchanted Evening (South Pacific) | William Michals | 3:43 |
| 9 | Evermore Without You (The Woman in White) | Ian McLarnon | 2:50 |
| 10 | Luck Be a Lady (Guys and Dolls) | Doug LaBrecque & Men | 3:05 |
| 11 | Pie Jesu (Rising Sun) | Sarah Brightman feat. Paul Miles-Kingston | 3:55 |
| 12 | Send in the Clowns (A Little Night Music) | Siân Phillips with the NSO Ensemble | 4:38 |
| 13 | Not While I’m Around (Sweeney Todd) | Imelda Staunton & James McConville | 3:33 |
| 14 | Love Never Dies (Love Never Dies) | Sierra Boggess & Andrew Lloyd Webber | 6:13 |
| 15 | As Long as He Needs Me (Oliver!) (live) | Jodie Prenger | 3:10 |
| 16 | Starlight Express (Starlight Express) | Paul Nicholas & Paul Jones | 5:14 |
| 17 | Can You Feel the Love Tonight? (The Lion King) | John Barrowman | 3:37 |
| 18 | The Winner Takes It All (Mamma Mia) | Martine McCutcheon | 4:48 |
| 19 | Sandy (Grease) | John Travolta | 2:34 |
| 20 | Over the Rainbow (The Wizard of Oz) | Helen Hobson | 3:48 |