| 1 | A Man Alone (Theme From the Ipcress File) | John Barry and His Orchestra | 2:29 |
| 2 | Deadlier Than the Male | The Walker Brothers | 2:32 |
| 3 | Arabesque | The Ventures | 2:30 |
| 4 | The Look of Love (Theme From Casino Royale) | Dusty Springfield | 3:31 |
| 5 | Theme From Danger Man | Red Price & His Combo | 2:07 |
| 6 | The Silencers | Vikki Carr | 2:58 |
| 7 | Secret Agent Man | Al Caiola | 2:26 |
| 8 | Who Needs Forever (Theme From the Deadly Affair) | Astrud Gilberto | 2:50 |
| 9 | Theme From the Man From U.N.C.L.E. | The Challengers | 1:51 |
| 10 | The Last of the Secret Agents | Nancy Sinatra | 2:46 |
| 11 | Mission: Impossible | Lalo Schifrin & His Orchestra | 2:34 |
| 12 | Dr Goldfoot and the Bikini Machine | The Supremes | 2:22 |
| 13 | Our Man Flint | Billy Strange | 2:06 |
| 14 | Wednesday's Child (Theme From the Quiller Memorandum) | Matt Monro | 2:37 |
| 15 | Theme From Get Smart | Bob Crane, His Drums and Orchestra | 1:55 |
| 16 | We Should've (Theme From Modesty Blaise) | Cleo Laine & Ray Ellington | 2:54 |
| 17 | The James Bond Theme (Dr No) | Johnny & the Hurricanes | 2:15 |
| 18 | Burke's Law Theme | Wynton Kelly | 2:11 |
| 19 | Where the Bullets Fly | Susan Maughan | 2:30 |
| 20 | High Wire (Theme From Danger Man) | Brian Fahey & His Orchestra | 2:19 |
| 21 | Bye Bye (Theme From Peter Gunn) | Sarah Vaughan | 1:52 |
| 22 | Theme From Where the Spies Are | Jimmy Smith | 2:56 |
| 23 | The Liquidator | Shirley Bassey | 2:20 |
| 24 | I Spy | Roland Shaw & His Orchestra | 2:12 |
| 25 | Come Spy With Me | Smokey Robinson & The Miracles | 2:56 |