| 1 | Scarlet Begonias (2013 Remaster) | Grateful Dead | 4:20 |
| 2 | They Love Each Other (live at Barton Hall, Cornell University, Ithaca, NY, 5/8/77) | Grateful Dead | 7:29 |
| 3 | The Stranger (Two Souls in Communion) (live at Academy of Music, New York, NY, March 28, 1972) | Grateful Dead | 8:58 |
| 4 | Katie Mae (live at the Filmore East, New York City, NY, 5/15/70) | Grateful Dead | 4:38 |
| 5 | She's Mine (live at the Filmore East, New York City, NY, 5/15/70) | Grateful Dead | 2:54 |
| 6 | Empty Pages (live at Auditorium Theater, Chicago, IL, August 24, 1971) | Grateful Dead | 5:22 |
| 7 | Hurts Me Too (live at Academy of Music, New York, NY, March 28, 1972) | Grateful Dead | 9:23 |
| 8 | I'm a Hog for You (live at Manhattan Center, New York, NY, April 6, 1971) | Grateful Dead | 4:08 |
| 9 | Peggy-O (live in Englishtown, NJ, September 3, 1977) | Grateful Dead | 9:18 |
| 10 | Pain in My Heart (live in San Francisco, 1966) | Grateful Dead | 4:25 |
| 11 | I'm a King Bee (Previously Unissued live in San Francisco 1966 version) | Grateful Dead | 8:53 |
| 12 | Hard to Handle (live at Convention Hall, San Diego, CA, August 7, 1971) | Grateful Dead | 8:45 |
| 13 | Turn on Your Love Light (live at Fillmore East, February 13-14, 1970) | Grateful Dead | 30:28 |
| 14 | Brown-Eyed Women (live at Oakland Auditorium Arena, December 26, 1979) | Grateful Dead | 5:20 |
| 15 | Empty Heart (live, February / March, 1966) | Grateful Dead | 6:18 |
| 16 | It Must Have Been the Roses (live at the Great American Music Hall, San Francisco, CA, August 13, 1975) | Grateful Dead | 5:06 |
| 17 | Althea (live at Nassau Coliseum, May 15-16, 1980) | Grateful Dead | 8:23 |
| 18 | If I Had the World to Give (2013 Remaster) | Grateful Dead | 4:51 |
| 19 | To Lay Me Down (live, June 26/28, 1974) | Grateful Dead | 8:24 |
| 20 | Gangster of Love (live, Fillmore Auditorium, San Francisco, July 3, 1966) | Grateful Dead | 4:35 |
| 21 | Sugar Magnolia (live in Paris, 1972; 2001 Remaster) | Grateful Dead | 7:10 |
| 22 | Deep Elem Blues (live at Lakeland Civic Center, Lakeland, FL 11/28/80) | Grateful Dead | 4:59 |
| 23 | El Paso (live at Barton Hall, Cornell University, Ithaca, NY 5/8/77) | Grateful Dead | 4:51 |
| 24 | Easy to Love You (live at the Copps Coliseum, Hamilton, Ontario, Canada, March 22, 1990) | Grateful Dead | 5:58 |
| 25 | Standing on the Moon (live at Pine Knob Music Theater, Clarkston, MI, June 20, 1991) | Grateful Dead | 10:36 |
| 26 | Looks Like Rain (live in London, 1972) | Grateful Dead | 7:38 |
| 27 | Foolish Heart (live at Giants Stadium, East Rutherford, NJ, 7/10/1989) | Grateful Dead | 10:19 |
| 28 | Peggy-O (live at Charlotte Coliseum, Charlotte, VA, December 10, 1973) | Grateful Dead | 6:03 |
| 29 | Rosalie McFall | Grateful Dead | 2:53 |
| 30 | Lazy River Road (live at Dean Smith Center, University of North Carolina, Chapel Hill, NC 3/25/1993) | Grateful Dead | 6:55 |
| 31 | Jack-A-Roe (live, Tuscaloosa, May 17, 1977) | Grateful Dead | 5:52 |
| 32 | She Belongs to Me (live at Richmond Coliseum, Richmond, VA, November 1, 1985) | Grateful Dead | 7:54 |
| 33 | Sugaree (live at the Great American Music Hall, San Francisco, CA, August 13, 1975) | Grateful Dead | 7:56 |
| 34 | Crazy Fingers (2013 Remaster) | Grateful Dead | 6:42 |
| 35 | Are You Lonely for Me (live at Academy of Music, New York, NY, March 25, 1972) | Grateful Dead | 7:37 |
| 36 | How Sweet It Is (To Be Loved by You) (live at Academy of Music, New York, NY, March 25, 1972) | Grateful Dead | 7:57 |
| 37 | Second That Emotion (live at Fillmore East, New York City, April 1971) | Grateful Dead | 5:34 |
| 38 | Black-Throated Wind (live in Veneta, Oregon 8/27/72) | Grateful Dead | 7:01 |
| 39 | Looks Like Rain (live at Academy of Music, New York, NY, March 28, 1972) | Grateful Dead | 8:06 |
| 40 | Gimme Some Lovin' (live at the Knickerbocker Arena, Albany, NY, March 26, 1990) | Grateful Dead | 5:09 |
| 41 | Easy to Love You (live in Springfield, MA, September 3, 1980) | Grateful Dead | 4:31 |
| 42 | Just a Little Light (live at Knickerbocker Arena, Albany, NY, March 1990) | Grateful Dead | 4:51 |
| 43 | Blow Away (live at Knickerbocker Arena, Albany, NY, March 1990) | Grateful Dead | 11:39 |
| 44 | From the Heart of Me (live at Winterland, December 31, 1978) | Grateful Dead | 3:47 |
| 45 | Good Lovin' (live at Fillmore East, New York City, April 1971) | Grateful Dead | 2:30 |
| 46 | Drums (live at Fillmore East, New York City, April 1971) | Grateful Dead | 5:38 |
| 47 | Good Lovin' (live at Fillmore East, New York City, April 1971) | Grateful Dead | 14:47 |
| 48 | Not Fade Away (live at Oxford Plains Speedway, Oxford, ME 7/3/88) | Grateful Dead | 8:02 |