| 1 | Main Title (Cello Version) | Fred Steiner | 0:55 |
| 2 | Space Orbit / Charlie X / That's a Girl (Charlie X) | Fred Steiner | 1:22 |
| 3 | Kirk's Command / Charlie's Mystery / Charlie's Gift (Charlie X) | Fred Steiner | 3:04 |
| 4 | Card Tricks (Charlie X) | Fred Steiner | 1:42 |
| 5 | Zap the Antares / Kirk Is Worried (Charlie X) | Fred Steiner | 0:48 |
| 6 | Kirk's Command #2 / Chess Game (Charlie X) | Fred Steiner | 1:35 |
| 7 | Charlie's Yen (Charlie X) | Fred Steiner | 1:06 |
| 8 | Kirk Puzzled (Charlie X) | Fred Steiner | 0:52 |
| 9 | Zap Sam / Zap the Pistol (Charlie X) | Fred Steiner | 1:39 |
| 10 | Standoff (Charlie X) | Fred Steiner | 1:13 |
| 11 | Kirk Waits / Charlie in Control (Charlie X) | Fred Steiner | 1:10 |
| 12 | Charlie's Mad (Charlie X) | Fred Steiner | 1:11 |
| 13 | Zap Janice (Charlie X) | Fred Steiner | 0:58 |
| 14 | Zap the Cap (Charlie X) | Fred Steiner | 1:34 |
| 15 | Zap the Spaceship (Charlie X) | Fred Steiner | 1:28 |
| 16 | Zap the Broad / Charlie's Friend (Charlie X) | Fred Steiner | 2:04 |
| 17 | Goodbye Charlie / Finale (Charlie X) | Fred Steiner | 1:56 |
| 18 | Distant Spaceship / Hint of Danger (Mudd's Women) | Fred Steiner | 0:57 |
| 19 | Still in Danger / Meet Mr. Mudd / Three Venuses (Mudd's Women) | Fred Steiner | 2:00 |
| 20 | Venus Walks / Hello Girls (Mudd's Women) | Fred Steiner | 1:31 |
| 21 | Venus Aboard / Exit Mr. Mudd / Venus Aboard #2 / Strange Glances / The Last Crystal / Mudd Laffs (Mudd's Women) | Fred Steiner | 2:52 |
| 22 | Hello Ruth (Mudd's Women) | Fred Steiner | 1:05 |
| 23 | Eve to Magda / Mudd Plan / Mudd's Perfidy (Mudd's Women) | Fred Steiner | 1:09 |
| 24 | The Venus Drug / Dwindling Power (Mudd's Women) | Fred Steiner | 3:04 |
| 25 | Planet Rigel (Mudd's Women) | Fred Steiner | 0:43 |
| 26 | Space Radio (Mudd's Women) | Fred Steiner | 2:48 |
| 27 | Planet Rigel #2 / Eve Is Out (Mudd's Women) | Fred Steiner | 1:21 |
| 28 | Eve Cooks / Eve Is Tired / Pretty Eve (Mudd's Women) | Fred Steiner | 3:06 |
| 29 | Mudd's Farewell / Back in Orbit (Mudd's Women) | Fred Steiner | 1:26 |
| 30 | Space Cube / Condition Alert (The Corbomite Maneuver) | Fred Steiner | 1:24 |
| 31 | Quiet Cube / Radiation (The Corbomite Maneuver) | Fred Steiner | 1:13 |
| 32 | Cube Radiation (The Corbomite Maneuver) | Fred Steiner | 1:21 |
| 33 | Fesarius / Fesarius Approaches (The Corbomite Maneuver) | Fred Steiner | 2:07 |
| 34 | Hideous Balok (The Corbomite Maneuver) | Fred Steiner | 0:29 |
| 35 | Baby Balok (The Corbomite Maneuver) | Fred Steiner | 0:41 |
| 36 | The Enterprise / In the Chapel (Balance of Terror) | Fred Steiner | 1:26 |
| 37 | Romulan Agitato (Balance of Terror) | Fred Steiner | 0:59 |
| 38 | Romulan B.G. (Balance of Terror) | Fred Steiner | 0:43 |
| 39 | Romulan Theme (Balance of Terror) | Fred Steiner | 0:57 |
| 40 | Theme from Star Trek / Romulan Warship / Romulan Theme (Balance of Terror) | Fred Steiner | 0:57 |
| 41 | Romulan Centurion (Balance of Terror) | Fred Steiner | 0:38 |
| 42 | Big Ruk (What Are Little Girls Made Of?) | Fred Steiner | 0:58 |
| 43 | Meet Andrea / Android Kirk (What Are Little Girls Made Of?) | Fred Steiner | 1:12 |
| 44 | Ruk Protect / Ruk Attacks (What Are Little Girls Made Of?) | Fred Steiner | 3:18 |
| 45 | Ruk Attacks / Enter Andrea (What Are Little Girls Made Of?) | Fred Steiner | 1:51 |
| 46 | End Title (Cello Version) | Fred Steiner | 0:45 |
| 47 | Desilu I.D. | Fred Steiner | 0:04 |