| 1 | Opening Credits (Overture From the Marriage of Figaro) | Wolfgang Amadeus Mozart | 0:54 |
| 2 | The Music of the Night (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 5:35 |
| 3 | Nella Fantasia (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 5:26 |
| 4 | Somewhere (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 2:33 |
| 5 | Interview & Profile of Serendipity | Katherine Jenkins & Tim Rhys Evans | — |
| 6 | Organ Fugue BWV 578 (live, 2007-07-08: Margam Park, Port Talbot, UK) | Johann Sebastian Bach | 2:51 |
| 7 | Yr Arglwydd a Fendithied (live, 2007-07-08: Margam Park, Port Talbot, UK) | Serendipity | 2:54 |
| 8 | The Festival & Travels Over Past Year | Katherine Jenkins | — |
| 9 | L'Amore Sei Tu (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 3:05 |
| 10 | Welsh Medley (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 7:35 |
| 11 | My Special Guest Juan Diego Flórez | Katherine Jenkins | — |
| 12 | La Donna E' Mobile (live, 2007-07-08: Margam Park, Port Talbot, UK) | Juan Diego Flórez | 2:36 |
| 13 | Meeting Katherine | Juan Diego Flórez | — |
| 14 | I (Who Have Nothing) (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 2:34 |
| 15 | Requiem for a Soldier (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | — |
| 16 | Time to Say Goodbye (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | — |
| 17 | Juan Diego Flórez Background & Style | Katherine Jenkins & Juan Diego Flórez | — |
| 18 | Only Make Believe (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins & Juan Diego Flórez | 2:39 |
| 19 | Granada (live, 2007-07-08: Margam Park, Port Talbot, UK) | Juan Diego Flórez | 5:09 |
| 20 | Amazing Grace (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 3:21 |
| 21 | I Could Have Danced All Night (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 3:05 |
| 22 | We'll Meet Again (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 4:19 |
| 23 | Non Ti Scordar di Me (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins & Juan Diego Flórez | 4:04 |
| 24 | We'll Keep a Welcome (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 3:12 |
| 25 | Hen Wlad Fy Nhadau (live, 2007-07-08: Margam Park, Port Talbot, UK) | Katherine Jenkins | 2:44 |
| 26 | End Credits | Katherine Jenkins | — |
| 27 | Ave Maria (live, S4C) | Katherine Jenkins | — |
| 28 | Laudate Dominum (live, S4C) | Katherine Jenkins | — |
| 29 | Canon Lan (live, S4C) | Katherine Jenkins | — |
| 30 | Nella Fantasia | Katherine Jenkins | — |