| 1 | Back for Good (Recorded at BBC Radio 2) | Gary Barlow | 3:29 |
| 2 | This Is Me (Recorded at Wogan House) | Keala Settle | 3:56 |
| 3 | Perfect Symphony (Recorded at Wogan House) | Matteo Bocelli & Andrea Bocelli | 4:23 |
| 4 | AnyWay (Recorded at Abbey Road, 2009) | Paul McCartney | 3:39 |
| 5 | Ain't No Sunshine (Recorded at BBC Radio 2) | Chris Rea | 2:29 |
| 6 | Promises (Recorded at Wogan House) | Rick Astley | 4:22 |
| 7 | Ordinary People (Recorded at BBC Radio 2) | John Legend | 4:23 |
| 8 | Love Is a Losing Game (Recorded at BBC Radio 2) | Amy Winehouse | 2:48 |
| 9 | Too Good at Goodbyes (Recorded at BBC Radio 2) | Sam Smith | 3:56 |
| 10 | Is This Love (Recorded at BBC Radio 2) | Rag'n'Bone Man | 3:51 |
| 11 | Never Let Me Go (Recorded at BBC Radio 2) | Florence + the Machine | 4:28 |
| 12 | Songbird (Recorded at BBC Radio 2) | Christine McVie | 3:02 |
| 13 | Sign of the Times (Recorded at BBC Radio 2) | Midge Ure | 4:04 |
| 14 | Fields of Gold (Recorded at BBC Radio 2) | Katie Melua | 3:32 |
| 15 | Young Hearts Run Free (Recorded at BBC Radio 2) | The Shires | 3:31 |
| 16 | The Night Will Always Win (Recorded at Manchester Cathedral, 2011) | Elbow | 4:22 |
| 17 | This Isn't Everything You Are (Recorded at BBC Radio 2) | Snow Patrol | 4:49 |
| 18 | Tiring Game (Recorded at BBC Radio 2) | John Newman | 3:30 |
| 19 | Sea Fog (Recorded at BBC Radio 2) | Keane | 3:22 |
| 20 | Man of the Hour (Recorded at BBC Radio 2) | Norah Jones | 2:45 |
| 21 | Clown (Recorded at BBC Radio Theatre, 2015) | Emeli Sandé | 3:58 |